Design and synthesis of tetrahydropyridothieno[2,3-d]pyrimidine scaffold based epidermal growth factor receptor (EGFR) kinase inhibitors: the role of side chain chirality and Michael acceptor group for maximal potency.

نویسندگان

  • Chia-Hsien Wu
  • Mohane Selvaraj Coumar
  • Chang-Ying Chu
  • Wen-Hsing Lin
  • Yi-Rong Chen
  • Chiung-Tong Chen
  • Hui-Yi Shiao
  • Shaik Rafi
  • Sing-Yi Wang
  • Hui Hsu
  • Chun-Hwa Chen
  • Chun-Yu Chang
  • Teng-Yuan Chang
  • Tzu-Wen Lien
  • Ming-Yu Fang
  • Kai-Chia Yeh
  • Ching-Ping Chen
  • Teng-Kuang Yeh
  • Su-Huei Hsieh
  • John T-A Hsu
  • Chun-Chen Liao
  • Yu-Sheng Chao
  • Hsing-Pang Hsieh
چکیده

HTS hit 7 was modified through hybrid design strategy to introduce a chiral side chain followed by introduction of Michael acceptor group to obtain potent EGFR kinase inhibitors 11 and 19. Both 11 and 19 showed over 3 orders of magnitude enhanced HCC827 antiproliferative activity compared to HTS hit 7 and also inhibited gefitinib-resistant double mutant (DM, T790M/L858R) EGFR kinase at nanomolar concentration. Moreover, treatment with 19 shrinked tumor in nude mice xenograft model.

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عنوان ژورنال:
  • Journal of medicinal chemistry

دوره 53 20  شماره 

صفحات  -

تاریخ انتشار 2010